By Patrick S. Mariano
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Within the Bhopal catastrophe of 1984, nearly 2,000 citizens dwelling close to a chemical plant have been killed and 20,000 extra suffered irreversible harm to their eyes and lungs following the unintentional liberate of methyl isocyanate. This tragedy served to concentration overseas realization at the desire for governments to spot dangerous ingredients and support neighborhood groups in making plans how you can take care of emergency exposures.
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5. 6. 7. 8. Cookson, R. ; Costa, S. M. ; Hudec, J. Chem. Commun. 1969, 753. ; Sakurai, H. Nippon Kagaku Kaishi 1984, 152. Lewis, F. ; Bassani, D. ,I. Photochem. Photobiol. A. 1994, 81, 13. ; Matsunaga, K. J. Chem. , Chem. Commun. 1972, 313. Lewis, F. -I. J. Am. Chem. Soc. 1977, 99, 7991. Yang, N. ; Libman, J. 3'. Am. Chem. Soc. 1973, 95, 5783. Barltrop, J. A. Pure Appl. Chem. 1973, 33, 179. (a) Lewis, F. D. Adv. Photochem. 1986, 13, 165. (b) Lewis, E D. Acc. Chem. Res. 1986, 19, 401. 9. Lewis, F.
Sugimoto and c o - w o r k e r s 7~ have reported that a number of covalently linked phenanthrene-secondary amine systems undergo intramolecular N-H addition. 7~ No exciplex fluorescence is observed for these or other linked arene--secondary amine systems; however, the locally excited fluorescence of 53a---e is much weaker than that of 9-methyll~henanthrene. The analogous tertiary amines form fluorescent exciplexes but fail to form intramolecular adducts. The N-deuterated analog of 53a exclusively forms the syn N-D adduct.
D. Adv. Photochem. 1986, 13, 165. (b) Lewis, E D. Acc. Chem. Res. 1986, 19, 401. 9. Lewis, F. D. ; Fox, M. ; Elsevier: Amsterdam, 1988, Part C, p. 1. Photoaddition Reactions of Amines 37 10. Pienta, N. J. ; Fox, M. ; Elsevier: Amsterdam, 1988, Part C, p. 421. 11. Bunce, N. J. In Handbook of Organic Photochemistry and Photobiology; Horspool, W. ; CRC Press: Boca Raton, FL, 1995, p. 266. 12. Yoon, U. ; Mariano, P. ; Givens, R. ; Atwater, B. W. In Advances in Electron Transfer Chemistry; Mariano, P.