Download Biomembrane Electrochemistry by Blank M., Vodyanoy I. (eds.) PDF

By Blank M., Vodyanoy I. (eds.)

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6 A n g u l a r Resolved X A N E S . . . . . . . . . . 36 36 4O 43 1 Introduction 31 45 49 53 4 Band Structure Approach to X A N E S of M e t a l s 56 56 57 59 5 Conclusion . . . . . . . . . . . . . . . 64 6 References . . . . . . . . . . . . . . . 64 . . . . . . . 1 M u l t i p l e Scattering A p p r o a c h . . . . . . . . . . 2 B a n d Structure A p p r o a c h . . . . . . . . . . . 3 P r o b i n g the Local Density o f States . .

Also, the attenuation of the higher terms ×4(E) and ×5(E) with increasing kinetic energy is much less than that observed for tetrahedral clusters. By comparing the total cross section obtained from a full multiple scattering calculation shown in the upper part of Fig. 10 with the EXAFS term ~0~2 we observe that the two spectra are very similar above 3 Rydberg. This effect is determined by the destructive interference between the n > 3 contributions. The negative interference between n = 3 and n = 4 contributions is clearly shown in Fig.

20 K (~-'1 b tO Z" El Exp. Fig. 8. The experimental xa(k) signal (solid line) obtained from the measured g(k) as x3(k) = { ( g ( k ) - go)/ g o } - ~2(k) is compared with the theoretical ~(k). 30ctahedral Clusters In the octahedral clusters there are O - - M o - - O atoms in a collinear configuration. When there are atoms in collinear configurations, the scattering amplitude is enhanced due to the high probability of forward scattering. -66), The focusing effect determines the presence of multiple scattering contributions also at high kinetic energies of the photoelectron.

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